Micas 0939950170

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Micas
 0939950170

Table of contents :
Page 1
Titles
MICAS
REVIEWS In
Volume 13
S. W. BAILEY
The Authors:
MINERALOGICAL SOCIETY OF AMERICA
Page 1
Titles
Reviews in Mineralogy
Page 1
Titles
PREFACE and ACKNOWLEDGMENTS
Page 1
Titles
MICAS
FOREWORD
Page 1
Titles
MICAS
S. W. BAILEY
T ABLE of CONTENTS
I. CLASSIFICATION and STRUCTURES of the MICAS
S.W. Bailey
2.
CRYSTAL CHEMISTRY of the TRUE MICAS
.........................
.........................
............................
3.
The BRITTLE MICAS
v
Page 2
Titles
4.
ELECTROST A TIC ENERGY MODELS of MICAS
R.F. Giese, Jr.
5.
SPECTROSCOPY of MICAS
George R. Rossman
vi
Page 3
Titles
.........................
.................................
6.
OPTICAL PROPER TIES of MICAS
under the POLARIZING MICROSCOPE
.............
7. EXPERIMENT AL PHASE RELATIONS of the MICAS
David A. Hewitt &: David R. Wones
....................
vii
Page 4
Titles
8. PARAGENESIS, CRYSTALLOCHEMICAL CHARACTERISTICS,
and GEOCHEMICAL EVOLUTION of MICAS in GRANITE PEGMATITES
9.
MICAS in IGNEOUS ROCKS
viii
Page 5
Titles
........................
..........................
..................................
10.
MICAS in METAMORPHIC ROCKS
ix
Page 6
Page 7
Titles
Metamorphic controls on the occurrence and composition of biotite
Petrogenetic aspects of biotite
Optical methods; Chemical analyses of biotite
11.
F-OH and CI-OH EXCHANGE in MICAS with
APPLICA TIONS to HYDROTHERMAL ORE DEPOSITS
Stability relations
F-OH exchange experiments
Cation ordering
12.
ILLITE
Jan Srodofi de Dennis D. Eberl
Analysis of oriented preparations 510
Analysis of random preparations 512
xi
Page 8
Titles
13.
GLAUCONITE and CELADONITE MINERALS
APPENDIX
X-RAY POWDER PATTERNS of MICAS
xii
Page 1
Titles
1. CLASSIFICATION and STRUCTURES of the MICAS
S. W. Bailey
b)
c)
Page 2
Page 3
Titles
Table 1. Classification of the Micas
3
Tables
Table 1
Page 4
Page 5
Titles
a)
+ x.
b)
c )
+ x,
o
Page 6
Page 7
Titles
3T
Vo
I ( or
zG:
: x I
x
t z
Ir -: - -r- Y
x 2 Or
/ z
~ ..
/0 2M2
~o
II ----9 6H
Page 8
Page 9
Titles
-
...,
Vl +" ""... I I I'" I "'1'" ~ eo '"
- "" ...
-
N .~ ...-4 C; rD ~ ~ s ~ ~ ~ 0
E-.~ .~u_ .~u_~
..........
Page 10
Tables
Table 1
Page 11
Titles
11
Tables
Table 1
Page 12
Tables
Table 1
Page 1
Titles
2.
CRYSTAL CHEMISTRY of the TRUE MICAS
)
a
j


i
1
Page 2
Page 3
Titles
I
,
1
"
I
a
1
lS
Page 4
Page 5
Page 6
Page 7
Page 8
Tables
Table 1
Page 9
Titles
21
Tables
Table 1
Page 10
Titles
22
Tables
Table 1
Page 11
Titles
23
Tables
Table 1
Page 12
Tables
Table 1
Page 13
Tables
Table 1
Page 14
Tables
Table 1
Page 15
Tables
Table 1
Page 16
Page 17
Page 18
Titles
~V ...
12:
~
~ ...
~'\iMO+2
Page 19
Page 20
Page 21
Titles
t
~-\I
Page 22
Page 23
Page 24
Page 25
Page 26
Page 27
Titles
39
Tables
Table 1
Page 28
Page 29
Page 30
Page 31
Tables
Table 1
Page 32
Page 33
Titles
"
8
o
;!~
'"
o
::z,
;!;!
;!;!
"''''
o
~
.... ..,
c
eo
. 5
c
g
(ij
:;::
·
xx
-e
'"
91
'" '"
Xx
:::1
XX
-!:I
N
XX
~I
N
'"
'"
~I
N
"''''
N
....
:3
~I
xx
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N
.!.J....J....
xxx
N
~~
xx
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:::
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N
u
·
co
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... c
?:;I
:!;::
.z::=!
c .
~_g
.:::U
.... .
~e
?:;I
I
u ..
... u
u
45
'"
'"
"
.....
'"
...~
" '"
....
Page 34
Titles
'" N
Q,9-
,.,'"
d
...
3
o
o
'"
3
o
eo
~q,
'"
;l;~
"''''
~9:
o 0
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,., ....
o~o
;3~j
:! :!
o 0
q, q,
o 0
o 0
.. '"
o 0
-0
-
o
Z-56.6
-56.7
o
2
3
4
5
6
7
8
9A
INTERlAYER SEPARATION
Tables
Table 1
Page 22
Titles

10
INCREASE IN INTERLAYER SPACING (A)
Page 23
Page 24
Page 25
Titles
--~-------~~~
1M
----~~~---F~---
Tables
Table 1
Table 2
Page 26
Page 27
Page 28
Page 29
Titles
c
Tables
Table 1
Page 30
Titles
\ /
\
/
\
Tables
Table 1
Page 31
Titles

o •• 0 •
o ••

• •
o • 0 •
. .0. .
o •• 0 •
Page 32
Page 33
Titles
137
Page 34
Titles
ENERGY
Tables
Table 1
Page 35
Titles
SUMMARY
Page 36
Page 37
Titles
REFERENCES
141
Page 38
Titles
142
Page 39
Titles
143
Page 40
Titles
144
Page 1
Titles
5.
SPECTROSCOPY of MICAS
George R. Rossman
Page 2
Tables
Table 1
Page 3
Page 4
Page 5
Titles
z
500
-,C>.c::>...c:: s-, .c
~~~~~~ ~ ~ ~
+ +
.., ..,
o ~ ~
c:: dI Q,) dI dI Q)
'0
,
~
ggggggggg
~ct
~ ~
,
e
u
.. ..
~~
....
~ '"
u u+ + + +
~ '"
-"-"
;;~
~ ~
I
Tables
Table 1
Table 2
Page 16
Page 17
Titles
Fe2+ M 2
-s 0
RT
RT
RT
RT
161
Tables
Table 1
Table 2
Page 18
Titles
••
i,
j
Page 19
Page 20
Titles
+
Page 21
Titles
•• 60-
b axis
b axis
AHIGMlss
1-4 MHz b axis
165
Page 22
Page 23
Titles
II. 7 T 27AI MASS
A
F - Phlogopite
B
o
Page 24
Page 25
Page 26
Tables
Table 1
Page 27
Titles
WAVENUMBER
Page 28
Page 29
Tables
Table 1
Page 30
Page 31
Page 32
Page 33
Titles
REFERENCES
177
Page 34
Titles
178
Page 35
Titles
179
Page 36
Titles
180
Page 37
Titles
181
Page 38
Page 1
Titles
6.
OPTICAL PROPERTIES of MICAS
under the POLARIZING MICROSCOPE
Page 2
Titles
MUSCOVITE
PHLOGOPITE
Page 3
Titles
I
II
I
I
llill
III I
mff
IT
ITT
1111111 "
185
Tables
Table 1
Page 4
Titles
III
mr

.... ,Wll_
III
I III
II III
III
I
®
Table I, continued.
186
Tables
Table 1
Page 5
Titles
Table I, concluded.
l
111111
UJJ
~
I fffl=11I
III
lL
I
187
Tables
Table 1
Page 6
Page 7
Titles
II
mr
-III
ill
189
Tables
Table 1
Page 8
Titles
Table 2, continued.
Remarks
yll!!.. OHZ II
rllb. OHZ 11
Wi 31
mi nnesot a t te
o
"
c:
"
o
"
c:
"
"
iii
o
o
o
o
:z:
j,..+.!..-'- 111--'-'---'-111 ,035
'1"11 ;;;_
190
Page 9
Titles
191
Tables
Table 1
Page 10
Page 11
Titles
~
Page 12
Page 13
Titles
>
i=
u
a:
EPHESITE Ca/(Ca+Na) MARGARITE
195
Page 14
Page 15
Page 16
Page 17
Page 18
Titles
REFERENCES
200
Page 1
Titles
7. EXPERIMENTAL PHASE RELATIONS of the MICAS
David A. Hewitt & David R. Wones
Page 2
Page 3
Titles
,o~----~------~~----------r-----------~r---
I,
800°C
700
600
sao
2
203
Tables
Table 1
Page 4
Page 5
Titles
o 0 01 ••
Tables
Table 1
Table 2
Page 6
Titles
206
Page 7
Tables
Table 1
Page 8
Titles
~
e
a:
~
~
Xmu
TOC
Alkf".SlIf
PH O=I.OOOBars
[exce s s 5;02 and H20)
700
650
600
550
And
Sill
And
Ab. •• Ms,,· And
P9 ... Ms ... And
And
10
08
06
ot.
02
500+-~~--,---~--_r--~--_.--~--_.~~--__+
O~
208
Page 9
Tables
Table 1
Page 10
Titles
THE SYSTEM
Abbreviations
Temperature It)
a
Temperature It)
210
Tables
Table 1
Table 2
Page 11
Tables
Table 1
Page 12
Tables
Table 1
Page 13
Page 14
Titles
'"
.3

,
1.1 1.2
214
Page 15
Titles
..:

Tables
Table 1
Page 16
Page 17
Titles
B
+
-15
o
'"
'"
.3
Ternper o tur e ;? C
217
Tables
Table 1
Page 18
Tables
Table 1
Page 19
Page 20
Titles
Sonidine + H.mo"t. + Gal
o
./
500
700
Temperature,OC
900
1100
-20 c_t
MSjLC
+ + o·
Ks Cor ..
(Hm) ~ 0:··
. ,
Cor
(,o.··
PFLUID = 2 kb
450
550
650
220
750
850
Tables
Table 1
Table 2
Page 21
Page 22
Titles
4 ~ Sodium Phlogopife
No M93 AI Si30lO (OH)2
o 0
Fo +L+V
o a I til
10
SPh+V
8 000
8
Mf + Fdsp
Temperature, "C
222
Page 23
Page 24
Titles
."
REV013C007_p225-256.pdf
Page 1
Page 2
Page 3
Titles
o
/
I
/
1[:"
/
k
~
L;t~
Ii
/0
o
o
o
-

o
... -
-
• .6c::::::c:J

"
Talc
Forsterite
Enstatite
'c-
!.I
227
Page 4
Titles
,
,
,
,
,~
"Ii
,~
,
,
,
,
,
,
,
'"
Page 5
Titles
Table I. (Continued on the next page)
Mica-Carbonate Reactions
229
Page 6
Page 7
Titles
T:C
sao
a.
T, ·C
231
Tables
Table 1
Page 8
Titles
o.
(Ph)
(Lc)
e.
f.
~~'"
En) tE
+
(So)
232
Tables
Table 1
Page 9
Tables
Table 1
Page 10
Titles
Table 2.
234
Page 11
Page 12
Titles
236
Page 13
Titles
1000 1100 1200 1300
Temperature, -c
.,.
1500
1400
-


900
5
800
15
20
237
Page 14
Titles
238
Page 15
Titles
~
(Ll
(Vap)
(0)
Temperature, °C
Page 16
Titles
2
600
700
.._
o,'
240
Tables
Table 1
Page 17
Titles
241
Page 18
Titles
01 2
Weight per cent H20 in system
P = 200 MPa
o
T("C)
Bt.PI.Af.Q.V
o 2 4 6 8 10 12
700
Tables
Table 1
Table 2
Page 19
Page 20
Titles
A K
Sill , Kfs
F -OpX
Cd
~ . ,
'"
E 2
, ":~:\\
'"
~
, ,
,
,
,
...
Page 21
Titles
&~En,VI
-lEn 1
Enl \0", ')'
\ ~En
T- ....
6
Page 22
Page 23
Titles
REFERENCES
247
Page 24
Titles
248
Page 25
Titles
249
Page 26
Titles
250
Page 27
Titles
251
Page 28
Titles
252
Page 29
Titles
253
Page 30
Titles
254
Page 31
Titles
255
Page 32
Titles
256
Page 1
Titles
8. PARAGENESIS, CRYSTALLOCHEMICAL CHARACTERISTICS,
and GEOCHEMICAL EVOLUTION of MICAS in GRANITE PEGMATITES
Page 2
Page 3
Page 4
Page 5
Page 6
Page 7
Page 8
Titles
264
Page 9
Page 10
Page 11
Titles
a.
, ... ,,",y! m; .. d''' .. ! , .... ''''.'1: a
.~t!/ L"-··{.~~~":·.'/ L_"':"":"
~ ". ,/
I ./ ~
" 'J!Y' '1
b.
....
c.
267
Page 12
Titles
a
e
b
...
f
268
Page 13
Page 14
Page 15
Page 16
Page 17
Titles
Li-Free
Page 18
Titles
,'"
,~.
Fe-Free
Si= 7
Si=8
Si=5
Si=6
Si=4
: - \ \
I _--=--=....\ \_
I --_I ,:~_
Page 19
Titles
Trioctahedral Micas
"
Tables
Table 1
Table 2
Page 20
Page 21
Titles
Tetrasilicic Micas
IV
Li=3
Li=4
Li=2
Li=l
I
... _ ... -_ ... - ~ \ \ ~
I \0 ,..-\ I 2 2 2
. ',..
0=1 ,~
0=2
0=0
\
277
Page 22
Titles
Li-Fe-AI Mica Volume
Subject to
Page 23
Page 24
Titles
a
b
Page 25
Titles
K/Rb
a
"~'il'
IIII1I111
c
K/Rb
b
d
\ \\,f" (UOlJ
\ \
~II~~~~
~IC (r~~ ~':co,
K/Rb
K/Rb
, ..
K/Rb
..
a., ppm
281
Page 26
Page 27
Page 28
Titles
b
Page 29
Page 30
Page 31
Page 32
Page 33
Page 34
Page 35
Page 36
Titles
REFERENCES
292
Page 37
Titles
293
Page 38
Titles
294
Page 39
Titles
295
Page 40
Titles
296
Page 41
Titles
297
Page 42
Page 1
Titles
9.
MICAS in IGNEOUS ROCKS
INTRODUCTION
OXYGEN AND WATER FUGACITIES
Page 2
Page 3
Titles
co
co
'"
+
'"
Dol I
of.ll ~ I e
11lf: 0'" .~..l ~
,£' &191 ~ ,£' ~i~ :
, ~ I -
oV" • ~~ .. dr oo;t ~
en"" 1:'1 en ~ I*)
~ ~ I~. ~ If tf·c
o ... I 0 ,0
.~ ,";'v-'c 2 9_N ~
~ S?/O~·I 0., ~ .f! ,?, _.s::; ·.!./I (jj
;z ~I Z 0':..
,(~ ;r.
:» .r ~~ .. ~y·
//
I.o~----~--~~~~~~~~
(Rb/K) feldspar x 104
Tables
Table 1
Page 20
Page 21
Page 22
Titles
K-Ar hornblende
FT titanite
'l K-Ar biotite
T. FT zircon FT apatite
......___ .~
o
apparent isotopic age (Ma)
-.-
distance from contact (meters)
320
Tables
Table 1
Table 2
Page 23
Page 24
Titles

·1;" •
~I:.
. .."' .
• •••
___ 1:?8o:~:!O
322
Tables
Table 1
Page 25
Page 26
Titles
I
"
§
.
,

"
REV013C009_p325-356.pdf
Page 1
Titles
MUSCOVITE IN IGNEOUS ROCKS
Page 2
Page 3
Titles
FeAt;!.1 \
Ti
No
K

......


Tables
Table 1
Page 4
Titles
MgO
Page 5
Titles
329
Page 6
Page 7
Page 8
Page 9
Page 10
Tables
Table 1
Page 11
Page 12
Titles

. .
• I
.~ .
;} ..., \ .
• • I. ••
.. ....
. '" ,. '" .
. ..,..1 ,-;t.. ,\. ... .,
.. ': ~....... . .. ~.,.... .
.' I... ~., ~aL1! ••
. . ..
Fe I(Fe + Mil)
i
t
temperature -
336
Tables
Table 1
Page 13
Page 14
Titles
X phlogopite
Fe+2/(Fe+2+ Mg)
Tables
Table 1
Page 15
Titles
mole fraction phlogopite
Tables
Table 1
Page 16
Titles
(4)
Page 17
Titles
200 ~--~---.--~--r--'---r--'-'
o
biotite 8180 (%0, SMOW)
Tables
Table 1
Page 18
Page 19
Titles
ionic radii (AO)
Tables
Table 1
Page 20
Titles
MgO
Mg
Heinrich (1946)
FeO+MnO
Mg
Foster (1960)
Neilson + Haynes (1973)
344
Page 21
Titles
... .
·
.
·
• :- •• I
...... ~ ...
••• ,.:, .",1' ,
.~ ..
. , .. ;wt'A1"·'
, .. "e; bt»f)~···
. .. . .
· ..
o •
wt. % AIP3 in rock
s
:.c
+
~.

,
.
Fe+2/(Fe+2+Mg) rock
345
Tables
Table 1
Page 22
Titles
MgO
I
I
m I /
o 00' /
/'~,l
:8 .1\
total Fe as FeO
346
Page 23
Titles
347
Page 24
Page 25
Titles
REFERENCES
349
Page 26
Titles
350
Page 27
Titles
351
Page 28
Titles
352
Page 29
Titles
353
Page 30
Titles
354
Page 31
Titles
355
Page 32
Titles
356
Page 1
Titles
10.
MICAS in METAMORPHIC ROCKS
Page 2
Titles
Group I: The dioctahedraZ white micas
Group II: The trioctahedraZ dark micas
Page 3
Titles
o
"
- '"
'"
'"
~ .~
-g =f
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"
- '"
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a;
u
a;
u
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o C
5 ~I
~ ~!
" E
" '"
o ,_
z +"
]59
Page 4
Titles
(I.A) Observed chemicaZ variation of the white micas,
Page 5
Titles
(K s p) "----+-----:;J~
(An)
Page 6
Titles
MARG
.. ;'"
MU
PG
Page 7
Page 8
Titles
c
L Mo+Fe
Page 9
Page 10
Titles
a
"
!
1
Low Phengite
b
High Phengite
gr--~-!~~~~~~ j
- ,...,-
U '"
~\C .......... ."M-:r
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
00"1"'" .... 0\(1'1 0 1f"! ......... N 11"\ NCO ..... -:r GO ...... 0 CO 04 0\...... ." ..,.
o:o:~"? ~ ~~ ..... "! ~ ~"': r; r;r; r; ~ ~ ~ ~ ~ ~o; 0-; '; \0 \0
GO
00"'0 0 U"l0 0 0 N 00 0-11"1'" '" If"\ N 11"1 ..... 0 NO If"I 0 VI If"I
_ ~ _ _ _ _ _ _ _ _ 0 _ - ~N
N~NM~~"'~"'_D~NNMM.,~~~O~NN~~M_.,.~"'D~_~~mm~-~~~
. ..
0-0
~~~~M~~NN~N~NNN~~~
------- -
.0 ••
~S s
> ••
m_
!lIN
· .
· "
..
· . ~
~~~M~~~NNNNNNNNNNNNNNN~~~~~~~~~~~~~~~~~~
-----.__",,__, __ -- - -.__",,__,-
gB=~Bg=~~~2~~~2~~g~2~=gg~~~~~g~~~I~:~~I~
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
1!
. ~
" ~
_....._ ,;-;.;
M N~NM~"'~~O"'~~~.N~~~
~ gg~=Sg=~~S~~~8~o~o
583
Tables
Table 1
Table 2
Table 3
Table 4
Page 40
Titles
N~~~~~~N~~~~r"'IO~~~~~~~~~~NNMN"""""~~~~~~~
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
~ •• MMMMMNNNNNNNNNNNNNNNNN""_"""""""""""""""""""""""""""_""",,
- ---- ......... ...__.,___,,--------
............ .......... ~-------
~N~~NNMNMM~~OMN~~O~NMN"NM~~M~~~~M~MNNM~O~~~
OON~~NO~~NOMO~MONN~NMON~NOOMOMOM~~~~~~M~OM~
..
>
",,l!
~c:~~~~~~~~~~~~~~~~~~~~-;-;c:~~~~~~~~~~~~~~~~
.;
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
__ ........... __ ....._.,___. ~ -...,...._.._
-- .......... - .......... ....-... .. ,........_., - _.. .... - .... - ....-... - .. ..
g~=B~B=~Bg=B=~~~2B~~A~2~:~g~2~~~2~~~~~!!~~~~~~~~=~~~~~
~r;~~~~"!r;~~~~"":~~ ~
N
'"
N
'"
'"
N
on
N
584
Tables
Table 1
Table 2

Polecaj historie