Advances in Organic Synthesis: Volume 8 [8] 9781681085654

Table of contents :
Cover
Advances in Organic Synthesis: Volume 8
Copyright
End User License Agreement
Contents
Preface
List of Contributors
1. Catalytic Tandem Reactions Triggered by the Introduction of a Carbonyl Function
Abstract
Introduction
Oxidation/Heteronucleophile Addition
Oxidation/C-Nucleophile Addition
Oxidation/Sophisticated Reactions
Carbonyl Installation/Reactions
Conclusion
Consent for Publication
Conflict of Interest
Acknowledgements
References
2. Synthetic Applications of Bifunctional Knölker Type Iron Complexes as (De)hydrogenation Catalysts
Abstract
Introduction
Hydrogenation
Knölker’s Iron Complex: Direct and Transfer Hydrogenation Reactions
Switching Fe/OH Complex to Fe/SiH Complex: Transfer Hydrogenation of Alkyne and Alkene
In Situ Generated Knölker Type Iron Complexes
(Cyclopentadienone)Iron Tricarbonyl Complexes: Direct Hydrogenation of Carbonyl Compounds
(Cyclopentadienone)Iron Tricarbonyl Complexes: Bicarbonate and CO2 Hydrogenation
Nitrile-Ligated (Cyclopentadienone)Iron Dicarbonyl Complexes: Hydrogenation of Carbonyl Compounds
Hydrogenation under Water Gas Shift Reaction (WGSR) Conditions
(Cyclopentadienone)Iron Tricarbonyl Complex: Aldehyde Reduction
Heterobimetallic Knölker Type Complex: Benzaldehyde Reduction
Asymmetric Hydrogenation
Chiral Iron Complexes: Hydrogenation of C=O Bond
Combining Achiral Knölker’s Complex and Chiral Additive: Hydrogenation of C=N Bond
Dehydrogenation
Knölker’s Iron Complex: Alcohol Dehydrogenation
(Cyclopentadienone) Iron Complexes: Alcohol Dehydrogenation
Methods Based on Dehydrogenative Alcohol Activation
Borrowing Hydrogen Methodology
Carbon-Nucleophile: Carbon-Carbon Bond Formation
Nitrogen-Nucleophile: Carbon-Nitrogen Bond Formation
Heterocycle Synthesis via C-C and C-N Bond Formation
Dynamic Kinetic Resolution of Alcohols
Concluding Remarks
Consent for Publication
Conflict of Interest
Acknowledgements
References
3. Superelectrophilic Activation of Alkynes, Alkenes, and Allenes
Abstract
Introduction
Superelectrophilic Activation of Alkynes
Superelectrophilic Activation of Alkenes
Superelectrophilic Activation of Conjugated Enynones
Superelectrophilic Activation of Allenes
Superelectrophilic Activation of Trifluoromethyl Substituted Alkynes and Alkenes
Concluding Remarks
Consent for Publication
Conflict of Interest
Acknowledgements
References
4. Chitosan and its Derivatives: Synthesis Strategy and Applications
Abstract
Introduction
Source of Chitin and Chitosan in Nature
Chitosan Properties
Synthesis of Chitosan Derivatives
Chitosan and its Derivatives: Antimicrobial Activity
Importance of the Degree of Deacetylation (DD) of Chitosan
Antimicrobial Action by Chelating Capacity of Chitosan
Toxicity of Chitosan and Chitosan Derivatives
Environmental Application of Chitosan - Derivatives
Entrapment of Bacterial Strains into Chitosan Beads for Bioremediation Application
Entrapment of Cells in Chitosan Beads
Chitosan/Derivatives for the Bioremediation of Oil-Polluted Seawater
Chitosan: Alternative Application as Coagulation Aid
Chitosan/Metal Oxides Nanocomposites
Chitosan: A Versatile Biocompatible Polymer
Concluding Remarks
Consent for Publication
Conflict of Interest
Acknowledgements
References
5. Synthesis of N-Containing Heterocycles via Hypervalent Iodine(III)-Mediated Intramolecular Oxidative Cyclization
Abstract
Three-Membered Ring
2H-Azirine
Aziridine
Four-membered Ring
Azetidines
Four-membered β-Lactam
Five-membered Ring
Pyrrole Derivatives
Indole Derivatives
Azoles
Six-membered Ring
Seven-membered Ring
Spiro- and Fused- Heterocycles
Conclusion and Future Perspective
Consent for Publication
Conflict of Interest
Acknowledgements
References
6. Advancements in Ionic Liquids for the Formation of Morita Baylis-Hillman Adducts
Abstract
Introduction
Origin and Features of Morita Baylis-Hillman reaction
Present Status in Context to Ionic Liquids
Imidazolium-based Ionic liquids
Concluding Remarks
Consent for Publication
Conflict of Interest
Acknowledgements
References
Subject Index
Cover back

Polecaj historie

Advances in Organic Synthesis [1 ed.] 9781681085647, 9781681085654

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challengin

175 103 26MB Read more

Advances in Organic Synthesis: Volume 10 [1 ed.] 9781681087436

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challengin

174 17 10MB Read more

Advances in Organic Synthesis: Volume 10 [10] 9781681087443

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challengin

176 53 7MB Read more

Advances in Organic Synthesis: Volume 12 [12] 9781681086835

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challengin

152 51 8MB Read more

Recent Advances in Polyphenol Research, Volume 8 (Recent Advances in Polyphenol Research, 8) 9781119844761, 1119844762

Plant polyphenols are specialized metabolites that constitute one of the most common and widespread groups of natural pr

167 21 21MB Read more

Advances in Organic Synthesis [1 ed.] 9781681086804

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challengin

151 22 13MB Read more

Parma Eldalamberon Volume 8 [8]

1,369 174 5MB Read more

Fundamentos de Matemática Elementar volume 8 [8]

The 6th Edition of Fundamentos de Matemática Elementar, volume 8, in brazilian portuguese. This book presents a careful,

1,167 130 92MB Read more

Organic Chemistry [8 ed.] 0840054440, 9780840054449

Master organic chemistry with the help of this proven best-seller! John McMurry's ORGANIC CHEMISTRY is consistently

3,465 458 220MB Read more

The Organic Chemistry of Drug Synthesis [Volume 5] 0471589594

The Organic Chemistry of Drug Synthesis, Volume 5 covers the literature on the synthesis of medicinal agents from 1988-1

560 83 2MB Read more